In the Adrenalin software, Performance tab, Tuning section, verify that the Default profile is selected and there is not an overclock applied. You can also click on the gear Settings icon in the top right corner and perform a Factory Reset if any settings have been changed. On the Metrics tab you can enable the Overlay to monitor temperatures in game, you can also enable logging to save an output of the values.
Ryzen R7 5700X | B550 Gaming X | 2x16GB G.Skill 3600 | Radeon RX 7900XT