You need to give more information on your computer hardware and software including Windows version, AMD Driver version, MAKE & Model of motherboard, CPU, GPU, & PSU.
At 750 watt PSU should be plenty of power unless it is defective in its outputs.
Also what do you mean that you have the RX590 connected via a RISER Cable? Something similar to this:
How are the monitiors connected? Via HDMI, DP, DVI, etc? Any adapters installed connected to the monitors?
Can you connect the GPU card directly on the motherboard's PCIex16 lane and see if both monitors works correctly? Could be the Riser may not be compatible with the RX590.