How do you have both Monitors connected to the GPU card using the GPU DP Ports?
What is different, as far as features goes, between the 27" and 32" monitors?
Here are the Spec from XFX concerning the outputs on your GPU card: https://www.xfxforce.com/shop/xfx-amd-radeon-tm-rx-6900-xt-gaming-graphics-card-with-16gb-gddr6-amd-...

Does both 32" Monitors have both DP and HDMI Input connections or just DP Input connections?
If they also have a HDMI Input connection try connecting one with DP and the other with HDMI and see if both shows up or are recognized by Windows.
If they are strictly DP Monitors with no HDMI inputs you can try and purchase a Active HD 4K HDMI>DP adapter and see if it works that way.
What shows in both Windows Settings - Display and Device Manager?
Do you have the 32" Monitor drivers installed by any chance?