The adrenalin software can not change CPU settings at all, i still wonder why AMD hasn't removed the overclock button for it.
To overclock your CPU you need to install Ryzen Master or do it manually in the BIOS (recommended).
Ryzen master has it's own issues and should be avoided in my opinion due to it's incompatibilaty with windows 11 core isolation.
Ryzen master will not even boot on any standar Windows 11 so you better of using your BIOS to overclock.
It's not easy to do so be carefull.