Dual Graphics is based on AMD DX11 Crossfire technology.
Therefore you should make sure that you only have one primary display output otherwise you will not be able to switch it on.
The primary display output should normally be the discrete graphics card since it is normally the most powerful GPU versus the APU graphics.
If this is the case then the primary display output should be the "PCIe Device" in BIOS rather than the iGPU graphics.
If you try to turn on Crossfire with a display output lead connected to the primary and secondary GPU in a normal (non-APU) DX11 Crossfire setup, Crossfire will not enable and you may not see the option to enable AMD Crossfire in Radeon Settings depending on the software version.
You can normally only Crossfire AMD GPUs with the same GPU architecture - unless the later generation GPU is a "re-badge".
So for example I can DX11 Crossfire an R9 Fury X with an R9 Nano and/or an R9 Fury card. They are all Fiji based GPUs.
I cannot DX11 Crossfire an R9 Fury X with an RX480, since one is Fiji and the other is Polaris.
I need to go now but here are some quick links to the GPUs.
AMD Radeon R7 250 - NotebookCheck.net Tech
AMD Radeon HD 7750 Specs | TechPowerUp GPU Database