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On the right side on the screen there are 3 buttons, press the "+" button in the middle twice and select Gaming, save your settings and you should get a notification that FreeSync has been enabled. You may have to select & save something other than Gaming (Multimedia, Photos, etc.) if Gaming is already selected and then reselect the Gaming option.
That's how I re-enabled FreeSync on my HP Envy 32 Media Display with an RX 480 after installing ReLive on a machine that was previously working properly with Catalyst.