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Actually I think this is a might be a Software Bug, but your hardware might be high end enough to handle the highest settings as well.
If there is game detection information then mostly in the past at least I see that changing the slider will result in an optimization on high end titles.
I tend to run demanding games, like Tom Clancy's the Division and the AMD Gaming Evolved Raptr App definitely helped there.
However after looking at this post I can see an example where I would expect optimization to change settings and it does not.
If you are still using the Raptr Gaming Evolved App you could file a Bug / Question at Raptr Support here: Support : Plays.tv Support