The M5 255 in your laptop does not have any display connections or the Universal Video Decoder, so you only have the gaming and system tabs present in Radeon Settings. The integrated GPU inside your laptop is wired to the display.
To configure an application to use the discrete GPU you need to open Radeon Settings > Preferences > Additional Settings.
In CCC Slim, navigate to Switchable Graphics Application Settings. This area will allow you to select which 3D application uses the Integrated GPU or the High Performance GPU. Add the application to CCC and select High Performance Mode to ensure that the High Performance GPU is used. Note, it is recommend to have the laptop plugged in and Windows configured to High performance mode in the Control Panel > Power options to ensure you get the best possible performance.
Thanks for the help but I can't use it as I found a guide how to get a Catalyst menus while using Crimson and since I had no problems with Catalyst I'll just keep it this way as Crimson gave me many degrades as giant preformance drops from December till Mid-February (Basically most apps ran at 10-20fps)
Again, thanks for the help and I had no idea Crimson had aditional options.