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When did the issue start? What was the first broken driver? Always with Windows 10?
For me even with CCC on a fresh install of 10 I could not disable CrossFire on some games, yet that CCC worked fine in 8.1. Or on 10 it would randomly work until I updated.
For now, it might be worth playing XYZ in borderless windowed mode to only render from GPU0. And submit a report to AMD so they have some more info on the issue.
This issue has been around since crimson hit its sweet 16 and still nothing has been done to fix it. Only workaround is to open "additional settings" in crimson and disable CF all together when playing games that dont support it. Playing in windowed mode while CF still is active will also lower your FPS so with every game you want to use single card for CF must be disabled.
I can turn off crossfire effectively through my CCC but yes, the profile settings it clearly isn't working as the games crash from crossfire running when they are not compatible. I too only had these problems since Crimson hit 16+