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Here is a AMD Video Guide on how to configure Multiple Monitor Setups:
This should help you setup your displays in Extended mode.
Thanks very much for the help.You have given me hope there is a solution to my problem.
I have taken the 2450 out of the machine but will install it again if I can find the right control center.
Do I need another version or am I not using it right?
Just to clarify, the MV 2450 was specifically designed for Win XP systems, in order to enable 4 displays in that OS. With any other OS you will be limited to 2 displays on this card, the MV 2460 was the upgrade for this and works with 4 Displays with Win VISTA or higher.
As long as you are only trying to get 2 displays working with Win 7 then you will be able to. Please go to the follow link and select the appropriate boxes as show below, then chose which OS you are using and click "Display Results":
(Note: If the OS is not listed then that card does not have drivers supported for it)